Gold‐Catalyzed C− H Functionalization Polycondensation for the Synthesis of Aromatic Polymers


Journal article


Eric R King, Joshua Tropp, Naresh Eedugurala, Lauren E Gonce, Sonia Stanciu, Jason D Azoulay
Angewandte Chemie, vol. 59(49), 2020, pp. 21971-21975


Cite

Cite

APA   Click to copy
King, E. R., Tropp, J., Eedugurala, N., Gonce, L. E., Stanciu, S., & Azoulay, J. D. (2020). Gold‐Catalyzed C− H Functionalization Polycondensation for the Synthesis of Aromatic Polymers. Angewandte Chemie, 59(49), 21971–21975. https://doi.org/10.1002/anie.202011426


Chicago/Turabian   Click to copy
King, Eric R, Joshua Tropp, Naresh Eedugurala, Lauren E Gonce, Sonia Stanciu, and Jason D Azoulay. “Gold‐Catalyzed C− H Functionalization Polycondensation for the Synthesis of Aromatic Polymers.” Angewandte Chemie 59, no. 49 (2020): 21971–21975.


MLA   Click to copy
King, Eric R., et al. “Gold‐Catalyzed C− H Functionalization Polycondensation for the Synthesis of Aromatic Polymers.” Angewandte Chemie, vol. 59, no. 49, 2020, pp. 21971–75, doi:10.1002/anie.202011426.


BibTeX   Click to copy

@article{eric2020a,
  title = {Gold‐Catalyzed C− H Functionalization Polycondensation for the Synthesis of Aromatic Polymers},
  year = {2020},
  issue = {49},
  journal = {Angewandte Chemie},
  pages = {21971-21975},
  volume = {59},
  doi = {10.1002/anie.202011426},
  author = {King, Eric R and Tropp, Joshua and Eedugurala, Naresh and Gonce, Lauren E and Stanciu, Sonia and Azoulay, Jason D}
}

Homogeneous gold catalysis enabled the C−H functionalization polycondensation of alkyne-containing comonomers and heteroarene nucleophiles (see scheme). The polymerization is broad in scope and proceeded with remarkable efficiency to produce high molecular weight aromatic copolymers. These results highlight the untapped utility of gold in the construction of new macromolecular systems.




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